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Effect of Tetraphenylphenyl-Modified Fumed Silica on Silicone Rubber Radiation Resistance

文献类型: 外文期刊

作者: Diao, Shen 1 ; Zhang, Shengyou 1 ; Yang, Zhizhou 1 ; Feng, Shengyu 1 ; Zhang, Changqiao 1 ; Wang, Zhaohua 2 ; Wang, Gu 1 ;

作者机构: 1.Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China

2.Shandong Acad Agr Sci, Inst Applicat Atom Energy, Jinan 250100, Peoples R China

3.Beijing Guodian Futong Sci & Technol Dev Co Ltd, Beijing 100070, Peoples R China

4.China Elect Power Sci & Technol Inst, Beijing 100192, Peoples R China

关键词: radiation resistance;silicone rubber;tetraphenylphenyltriethoxysilane;fumed silica

期刊名称:JOURNAL OF APPLIED POLYMER SCIENCE ( 影响因子:3.125; 五年影响因子:2.754 )

ISSN: 0021-8995

年卷期: 2011 年 120 卷 4 期

页码:

收录情况: SCI

摘要: Two kinds of treated fumed silica were prepared by treatment with either tetraphenylphenyltriethoxysilane (TPHTS) or both tetraphenylphenyltriethoxysilane and hexamethyldisilazane (TPHMTS), and were used as reinforcing filler for silicone rubber. The resistance to irradiation of the silicone rubber obtained was investigated by gamma ray of dose 500 kGy in air. The mechanical properties and the average molecular weight between crosslinking points (Mc) of the silicone rubber were determined before and after irradiation. The results show that the fumed silica treated by tetraphenylphenyltriethoxysilane (TPHPHS) can effectively improve the radiation resistance of silicone rubber while the fumed silica treated by both tetraphenylphenyltriethoxysilane and hexamethyldisilazane (MM(N)) cannot only effectively improve the radiation resistance of silicone rubber but also has excellent reinforcing effect on silicone rubber. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 120: 2440-2447, 2011

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