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Synthesis and Characterization of Gelatin-Polydimethylsiloxane Graft Copolymers

文献类型: 外文期刊

作者: Zhang, Meng 1 ; Wu, Yuanjuan 3 ; Zhang, Qingsi 2 ; Xia, Yongmei 1 ; Li, Tianduo 1 ;

作者机构: 1.Jiangnan Univ, Sch Chem & Mat Sci, Wuxi 214122, Peoples R China

2.Shandong Inst Light Ind, Shandong Prov Key Lab Fine Chem, Jinan 250353, Peoples R China

3.Shandong Acad Agr Sci, Cent Lab, Jinan 250100, Peoples R China

关键词: gelatin;polydimethylsiloxane;graft copolymer;X-ray diffraction;glass transition temperature

期刊名称:JOURNAL OF APPLIED POLYMER SCIENCE ( 影响因子:3.125; 五年影响因子:2.754 )

ISSN: 0021-8995

年卷期: 2011 年 120 卷 4 期

页码:

收录情况: SCI

摘要: Gelatin-polydimethylsiloxane (PDMS) graft copolymers were prepared through the reaction between gelatin and alpha-[3-(2,3-epoxypropoxy) propyl]-omega-butyl-PDMSs. The copolymers were characterized by FTIR and (1)H-NMR spectra. As proved by wide angle X-ray analysis, a new characteristic crystalline peak appeared after the bonding of PDMS to gelatin chains. The microstructure and the elemental identification of gelatin and copolymers were followed through scanning electron microscope with energy dispersive spectrometer. The glass transition temperature of gelatin and copolymers were obtained by differential scanning calorimetry analysis. (C) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 120: 2130-2137, 2011

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