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Bis{mu-2,2 '-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}bis[(thiocyanato-kappa N)iron(III)]

文献类型: 外文期刊

作者: Hao, Lujiang 1 ; Mu, Chunhua 2 ; Kong, Binbin 1 ;

作者机构: 1.Shandong Inst Light Ind, Coll Food & Biol Engn, Jinan 250353, Peoples R China

2.Shandong Acad Agr Sci, Maize Res Inst, Jinan 250100, Peoples R China

期刊名称:ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE ( 影响因子:0.347; 五年影响因子:0.278 )

ISSN: 1600-5368

年卷期: 2008 年 64 卷

页码:

收录情况: SCI

摘要: The title compound, [Fe-2(C16H14N2O2)(2)(NCS)(2)], is isostructural with the Mn-III-containing analogue. Each Fe-III atom is chelated by a tetradentate 2,2'-[ethane-1,2-diylbis(nitrilomethylidyne)] diphenolate ligand and by the N atom of a thiocyanate anion, in a square-pyramidal arrangement. The complex molecules form centrosymmetric dimers, with an Fe-O contact of 2.549 (3) angstrom, trans to each thiocyanate anion, completing a distorted octahedral coordination geometry.

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