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Triaqua(2,2 '-bipyridine-kappa(2)N,N ')(5-nitroisophthalato-kappa O(1))zinc(II) monohydrate

文献类型: 外文期刊

作者: Hao, Lujiang 1 ; Liu, Xia 2 ;

作者机构: 1.Coll Food & Biol Engn, Shandong Inst Light Ind, Jinan 250353, Peoples R China

2.Shandong Acad Agr Sci, Maize Res Inst, Jinan 250100, Peoples R China

期刊名称:ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE ( 影响因子:0.347; 五年影响因子:0.278 )

ISSN: 1600-5368

年卷期: 2008 年 64 卷

页码:

收录情况: SCI

摘要: In the title compound, [Zn(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]center dot H(2)O, the Zn(II) cation is hexacoordinated by a chelating 2,2'-bipyridine ligand, one carboxylate O atom from a 5-nitro-isophthalate dianion and three water molecules in a slightly distorted octahedral geometry. The structure contains isolated neutral complexes, in contrast to coordination polymers formed by Mn(II), Co(II) and Cu(II) with the same ligand set. An extensive network of hydrogen bonds is formed between the water molecules and the carboxylate groups.

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