Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution
文献类型： 外文期刊
作者： Ma Zheng 1 ; Dong Xiaoxia 1 ; Hu Yufeng 2 ; Zhang Bosong 1 ; Xu Changying 1 ; Liu Yansheng 2 ;
作者机构： 1.Shandong Acad Agr Sci, Agr Resources & Environm Inst, Shandong Prov Key Lab Plant Nutr & Fertilizer, Jinan 250100, Peoples R China
2.China Univ Petr, State Key Lab Heavy Oil Proc, Beijing 102249, Peoples R China
关键词： ionic liquid;activity coefficients at infinite dilution;organic reactions
期刊名称：CHINESE JOURNAL OF CHEMICAL ENGINEERING （ 影响因子：3.171； 五年影响因子：2.853 ）
ISSN： 1004-9541
年卷期： 2013 年 21 卷 12 期
页码：
收录情况： SCI
摘要： It is important to know how ILs (ionic liquids) influence organic reaction. In this paper, activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs, such as Diels-Alder, esterification and Friedel-Crafts reaction, the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.
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