Asymmetric Synthesis of Three Alkenyl Epoxides: Crafting the Sex Pheromones of the Elm Spanworm and the Painted Apple Moth
文献类型： 外文期刊
作者： Zhou, Yun 1 ; Wang, Jianan 2 ; Tian, Beijing 1 ; Zhu, Yanwei 1 ; Zhang, Yujuan 1 ; Han, Jinlong 1 ; Zhong, Jiangchun 2 ; Shan, Chenggang 1 ;
作者机构： 1.Shandong Acad Agr Sci, Inst Ind Crops, Jinan 250100, Peoples R China
2.China Agr Univ, Dept Appl Chem, Beijing 100193, Peoples R China
关键词： sex pheromone; alkenyl epoxides; elm spanworm; painted apple moth; asymmetric synthesis
期刊名称：MOLECULES （ 影响因子：4.6； 五年影响因子：4.9 ）
ISSN：
年卷期： 2024 年 29 卷 9 期
页码：
收录情况： SCI
摘要： A concise synthesis of the sex pheromones of elm spanworm as well as painted apple moth has been achieved. The key steps were the alkylation of acetylide ion, Sharpless asymmetric epoxidation and Brown's P2-Ni reduction. This approach provided the sex pheromone of the elm spanworm (1) in 31% total yield and those of the painted apple moth (2, 3) in 26% and 32% total yields. The ee values of three final products were up to 99%. The synthesized pheromones hold promising potential for use in the management and control of these pests.
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