A novel regulable enantioselective platform based on porphyrin tubular cage assemblies with controllable handedness
文献类型： 外文期刊
作者： Jiang, Yuying 1 ; Wang, Yutao 1 ; Cai, Da 1 ; Liu, Chao 2 ; Gao, Rui 1 ; Bi, Jingxiu 1 ; Liu, Pingxiang 1 ; Gao, Lei 1 ; Wang, Tianyu 2 ;
作者机构： 1.Shandong Acad Agr Sci, Inst Agr Qual Stand & Testing Technol, Shandong Prov Key Lab Test Technol Food Qual & Saf, Jinan Ind North Rd 202, Jinan, Shandong, Peoples R China
2.Univ Sci & Technol Beijing, Dept Chem, Beijing Key Lab Sci & Applicat Funct Mol & Crystal, Beijing 100083, Peoples R China
关键词： Controllable handedness; Enantioselective platform; Interfacial assembly; Porphyrin tubular cage
期刊名称：COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS （ 影响因子：5.2； 五年影响因子：4.7 ）
ISSN： 0927-7757
年卷期： 2023 年 658 卷
页码：
收录情况： SCI
摘要： Here, the first mono-molecule-diameter sized assembling film with controllable handedness is constructed upon air/water interfacial assembly of porphyrin tubular cage (PTC) with C60 fullerene. The assembling film can be a smart chiral sensing platform for electrochemical recognition of tryptophan (Trp) isomers. Resulting from the non-covalent interactions induced changeable handedness, the discriminating effect of L-and D-Trp is dependent on the chirality of assemblies. This work provides a new idea for developing regulable enantioselective platform.
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