Effect of storage states on stability of three organophosphorus insecticide residues on cowpea samples
文献类型： 外文期刊
作者： Bian, Yanli 1 ; Wang, Boning 1 ; Liu, Fengmao 1 ; Wang, Yihan 1 ; Huang, Hongwei 1 ;
作者机构： 1.China Agr Univ, Coll Sci, 2 Yuanmingyuan West Rd, Beijing 100193, Peoples R China
2.Shandong Acad Agr Sci, Inst Residue Technol, Shandong Acad Pesticide Sci, Jinan, Peoples R China
关键词： storage stability; organophosphorus insecticides; cowpea; storage state; enzyme
期刊名称：JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE （ 影响因子：2.614； 五年影响因子：2.945 ）
ISSN： 0022-5142
年卷期：
页码：
收录情况： SCI
摘要： BACKGROUND The stability of pesticide residues in stored samples is very important to ensure the quality of data about the residues. The evaluation of pesticide residues in food and environment samples is an important means to ensure food quality and protect consumers against potential dietary risks. Improper storage of pesticide residue samples may result in loss of pesticide and unreliable data, which could affect safety assessments. RESULTS The influences of storage conditions, including temperature (-20 degrees C, 4 degrees C, and ambient temperature) and sample state (homogenized state and coarsely chopped state) on the storage stability of dichlorvos, malathion, and diazinon on cowpea were studied. Dichlorvos and malathion were more stable in an homogenized state than in a coarsely chopped state. At 4 degrees C, the residual dichlorvos in the coarsely chopped state and the homogenized state, respectively, was 12% and 69%; the residual malathion was 26% and 92%, respectively. Dichlorvos suffered a large loss of 89% and 59% for coarsely chopped and homogenized cowpea, even at -20 degrees C. It was obvious that the stability of dichlorvos and malathion were more affected by storage state than diazinon. The stability of diazinon was significantly affected by temperature. The effect of storage state and temperature on stability is likely to be correlated with enzymes in the matrix, such as superoxide dismutase (SOD), catalase (CAT), and peroxidase (POD). CONCLUSION The optimal stable storage conditions for three organophosphorus insecticides residues on cowpea were in the homogenized state and under a lower temperature. (c) 2021 Society of Chemical Industry.
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